AN ANALYTICAL APPROACH TO ION TRANSPORT
IN THE INTERFACE REGION OF THE ERI AD
(ELECTROSPRAY)
ION SOURCE
A. D. Andreyeva, A. A. Elistratov*, L. N. Gall
Institute for Analytical Instrumentation RAS, Saint-Petersburg
*Institute for Cryptosystems, Communications and Informatics, Moscow
There is still a need for improvements
in interfacial systems of mass spectrometers with atmospheric pressure
ionization sources. The interface region is characterized by complicated
gaseous and electrodynamic conditions that strongly influence the total ion
transmission and ion beam characteristics at the entrance of the mass spectrometer.
In our work, we present a simple analytical model for the estimation of ion
beam characteristics at the exit of the interface region. The traditional
"nozzle--skimmer" system is investigated by ion transport modeling using
continuum-based approximation in the limit of low ion currents. The model
quickly builds smoothed ion trajectories in a supersonic gas jet and electric
field of the interface. It also builds the nozzle--skimmer ion current-voltage
characteristics in paraxial approximation.