A. N. Verenchikov, M. I. Yavor
Institute for Analytical Instrumentation RAS, Saint-Petersburg
The work studies the effect of stable
ion confinement in periodic and nonuniform electrostatic fields. As an
example of periodic systems, there are considered ion guides formed by
a sequence of lenses as well as electrostatic traps and multireflecting
time-of-flight mass spectrometers formed by ion mirrors. Using a first-order
approximation, it is shown that cylindrical and planar symmetric periodic
fields have focusing properties and retain ions near the axis of symmetry
in a wide range of energies. A new term "effective retaining potential"
is introduced to characterize stability of ion motion as an ability to
withstand external perturbations like electrostatic or magnetic deflection
as well as random ion scattering. Effects of nonlinear terms are observed.
It is shown that compensation of chromatic aberrations improves ion stability
in reflecting periodic systems.